منابع مشابه
Mechanistic Studies of Laccase/TEMPO Catalyzed Aerobic Oxidation of Alcohols
The reaction parameters for the Laccase/TEMPO system in the aerobic oxidation of aromatic alcohols were investigated. The optimized concentrations of laccase and alcohol were found to be 10 U/ml and 160 mM respectively. Under these conditions the use of 9 mol % TEMPO led to good conversions within 4 h. The optimum temperature for the reaction was found to be above room temperature (around 30°C).
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Crude cell-free preparations of Botrytis cinerea were found to oxidize straight-chain primary alcohols (except methanol), aromatic primary alcohols, and unsaturated primary alcohols. The resulting products were the corresponding aldehydes and an equal molar quantity of hydrogen peroxide.
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Current catalysts for the alcohol oxidation in fuel cells (typically noble metals-based) are susceptible to poisoning with intermediates like CO. Hence we decided to find superseded catalysts for methanol oxidation based on incorporation of mixed oxides. In this research, a nano-size perovskite SrFeO3-δ (SrFeO3<su...
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Selective oxidation of alcohol in water using molecular oxygen as the terminal oxidant is mediated by rhodium porphyrin complexes. Addition of methanol to an aqueous solution of (TSPP)Rh(III) resulted in observation of the key intermediate porphyrin rhodium(III) methoxide species. The activation parameters for betaC-H elimination of Rh-alkoxide were evaluated.
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ژورنال
عنوان ژورنال: Journal of Japan Oil Chemists' Society
سال: 1970
ISSN: 1884-2003
DOI: 10.5650/jos1956.19.1087